Scoops of lunar soil still surprise half a century after Apollo 17. The latest astonishment comes from specks of glass “moon beads” that sparkle like confetti under laboratory lights.
Each bead measures under a millimeter and erupted 3.3 to 3.6 billion years ago, yet it keeps the Moon’s volcanic diaries locked inside.
The team behind the new analysis includes Thomas Williams, Stephen Parman, Alberto Saal, and Ryan Ogliore of Washington University in St. Louis and Brown University.
Molten basalt once blasted into vacuum, froze mid flight, and rained back as droplets now known as pyroclastic glass beads.
These eruptions behaved like the fiery fountains seen today on Kīlauea, launching material dozens of miles high.
Because no atmosphere cushioned the spray, the droplets cooled instantly and recorded chemical signals from deep lunar magma. That process turned them into perfect time capsules for planetary scientists.
Astronauts found the first orange deposit at Shorty Crater in 1972 and packed pounds of the vivid soil for study.
Those bright colors hinted at titanium rich magmas that differ from the darker green beads sampled elsewhere on the Moon.
Researchers prize the beads because they trap internal gases that never leaked to space. Melt inclusions inside similar beads carry 615 to 1,410 parts per million water, rivaling Earth’s upper mantle.
That unexpected moisture rewrote textbooks that once labeled the Moon bone dry. It also raised questions about how much volatile material escaped during the Moon forming impact.
The new study focuses less on what sits inside each bead and more on what clings to the outside. There, nanoscale minerals reveal the chemistry of eruption clouds that once roared above the surface.
Ogliore’s lab used a NanoSIMS instrument that bombards samples with ions and counts the fragments one atom at a time.
Complementary microscopes and an atom probe tomography system in partner institutions filled out the picture.
Earlier Apollo reports listed the beads’ colors but could not inspect coatings thinner than a red blood cell. Today’s gear slices those coatings like digital deli meat, mapping every element.
“We’ve had these samples for 50 years, but we now have the technology to fully understand them,” said Ogliore.
The shine comes from mounds of zinc sulfide just billionths of an inch high. In mineral form that compound is called sphalerite, the chief ore of zinc on Earth.
Each mound starts rich in iron where it touches the glass, then grades to purer zinc toward the top. That gradient suggests eruption clouds cooled and thinned as the beads rode outward.
Coatings on lunar beads elsewhere carry sodium chloride, gallium, or fluorine, supporting the idea that fire fountain gases were packed with volatile metals.
Those films are just a few hundred atoms thick, yet they store clues about pressure, temperature, and gas composition with a fidelity unmatched by larger rocks. They also explain why small beads can sparkle against a dusty gray landscape.
Knowing how volatiles behaved in ancient eruptions helps refine models of lunar resource distribution. Future astronauts looking for sulfur or zinc deposits might follow pathways mapped by these tiny mounds.
The coatings also record sulfur isotope shifts that trace gas flow, information that can calibrate seismic and orbital data about past volcanic vents.
Such cross checks are vital as NASA targets Artemis landing zones near similar pyroclastic plains.
These glass beads reveal that the Moon’s volcanic past was more dynamic than previously assumed. Rather than being geologically quiet, ancient eruptions threw material high into space, cooled it instantly, and preserved complex gas chemistry.
By identifying specific minerals on the bead surfaces, scientists can now trace how gas pressures dropped and compositions shifted within seconds. That kind of resolution reshapes how we think about volcanic eruptions in a vacuum.
These beads do more than tell us about the Moon, they offer a glimpse into how volcanic processes might look on other airless worlds.
Planets and moons without atmospheres, like Mercury or some asteroids, may also host surface materials with preserved eruption signatures if similar pyroclastic activity occurred.
Studying these processes in lunar samples gives researchers a benchmark for interpreting future samples from other missions, such as Mars’ moons or even returned asteroid regolith.
This broader view helps scientists compare geologic histories across the solar system and refine our understanding of how planetary bodies lose or retain volatiles.
Williams and colleagues now want to compare orange, green, and black beads across core samples to watch eruption styles evolve over minutes.
They will also hunt for any beads that show metallic zinc rather than sphalerite, a sign of even lower eruption pressures.
The Moon still keeps many secrets, but its glittering beads talk louder each time a new tool listens. Continued cooperation between microscopists and mission planners promises to turn more of that lunar whisper into a readable history.
The study is published in Icarus.
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